Using 1 -chloro-l-[~~N]nitrosocyclohexane, we have prepared five L-[a-'SN]arnino acids. The stereoselective electophillic hydroxyamination of (S)-acylbornane-l0,2-suftams, followed by ZnO/H+ reduction, and alkaline cleavage of the chiral auxiliary, gave the amino acids in 97.2-99.5 % e.e. By starti
Enantioselective syntheses of α-amino-β-hydroxy acids, [15N]-L-allothreonine and [15N]-L-threonine
✍ Scribed by Andrew Sutherland; Christine L. Willis
- Publisher
- Elsevier Science
- Year
- 1997
- Tongue
- French
- Weight
- 207 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0040-4039
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