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Enantioselective Pd-catalysed allylation with BINOL-derived monodentate phosphite and phosphoramidite ligands

โœ Scribed by K.N. Gavrilov; S.E. Lyubimov; S.V. Zheglov; E.B. Benetsky; V.A. Davankov


Book ID
108211470
Publisher
Elsevier Science
Year
2005
Tongue
English
Weight
194 KB
Volume
231
Category
Article
ISSN
1381-1169

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Binol-Derived Monodentate Phosphites and
โœ Manfred T. Reetz; Jun-An Ma; Richard Goddard ๐Ÿ“‚ Article ๐Ÿ“… 2005 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 154 KB

Recently three groups independently reported that binolderived monodentate phosphites 1 a, [1] phosphonites 1 b, [2] and phosphoramidites 1 c [3] are efficient ligands in rhodiumcatalyzed asymmetric olefin hydrogenation (ee values = 90-99 %; binol = 2,2'-dihydroxy-1,1'-binaphthyl). A preliminary