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Binol-Derived Monodentate Phosphites and Phosphoramidites with Phosphorus Stereogenic Centers: Novel Ligands for Transition-Metal Catalysis.

โœ Scribed by Manfred T. Reetz; Jun-An Ma; Richard Goddard

Book ID
101970139
Publisher
John Wiley and Sons
Year
2005
Weight
36 KB
Volume
36
Category
Article
ISSN
0931-7597

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Binol-Derived Monodentate Phosphites and
Binol-Derived Monodentate Phosphites and Phosphoramidites with Phosphorus Stereogenic Centers: Novel Ligands for Transition-Metal Catalysis
โœ Manfred T. Reetz; Jun-An Ma; Richard Goddard ๐Ÿ“‚ Article ๐Ÿ“… 2005 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 154 KB

Recently three groups independently reported that binolderived monodentate phosphites 1 a, [1] phosphonites 1 b, [2] and phosphoramidites 1 c [3] are efficient ligands in rhodiumcatalyzed asymmetric olefin hydrogenation (ee values = 90-99 %; binol = 2,2'-dihydroxy-1,1'-binaphthyl). A preliminary