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Binol-Derived Monodentate Phosphites and Phosphoramidites with Phosphorus Stereogenic Centers: Novel Ligands for Transition-Metal Catalysis

✍ Scribed by Manfred T. Reetz; Jun-An Ma; Richard Goddard

Book ID: 101564883
Publisher: John Wiley and Sons
Year: 2005
Tongue: English
Weight: 154 KB
Volume: 44
Category: Article
ISSN: 0044-8249
DOI: 10.1002/anie.200461624

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Binol-Derived Monodentate Phosphites and

Binol-Derived Monodentate Phosphites and Phosphoramidites with Phosphorus Stereogenic Centers: Novel Ligands for Transition-Metal Catalysis.

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Binol-Derived Monodentate Phosphites and

Binol-Derived Monodentate Phosphites and Phosphoramidites with Phosphorus Stereogenic Centers: Novel Ligands for Transition-Metal Catalysis

✍ Manfred T. Reetz; Jun-An Ma; Richard Goddard 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 154 KB

Recently three groups independently reported that binolderived monodentate phosphites 1 a, [1] phosphonites 1 b, [2] and phosphoramidites 1 c [3] are efficient ligands in rhodiumcatalyzed asymmetric olefin hydrogenation (ee values = 90-99 %; binol = 2,2'-dihydroxy-1,1'-binaphthyl). A preliminary