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Enantioselective Nucleophilic Formylation and Cyanation of Conjugated Enones via Michael Addition of Formaldehyde SAMP-Hydrazone

✍ Scribed by Lassaletta, Jose-María; Fernández, Rosario; Martín-Zamora, Eloísa; Díez, Elena


Book ID
120589535
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
129 KB
Volume
118
Category
Article
ISSN
0002-7863

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ChemInform Abstract: Asymmetric Michael
✍ D. Enders; Pascal Teschner; Robert Groebner; Gerhard Raabe 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 31 KB 👁 2 views

Asymmetric Michael Additions via 6-and 7-Membered Lactone SAMP-Hydrazones: Diastereo-and Enantioselective Synthesis of Substituted Lactone Esters. -High asymmetric inductions are achieved in the Michael addition of hydrazones (I) to α,β-unsaturated esters (II). Removal of the chiral auxiliary by ozo