Enantioselective Hydrogenation of β-Ketophosphonates with Chiral Ru(II) Catalysts
✍ Scribed by Tao, Xiaoming; Li, Wanfang; Ma, Xin; Li, Xiaoming; Fan, Weizheng; Zhu, Lvfeng; Xie, Xiaomin; Zhang, Zhaoguo
- Book ID
- 120063773
- Publisher
- American Chemical Society
- Year
- 2012
- Tongue
- English
- Weight
- 363 KB
- Volume
- 77
- Category
- Article
- ISSN
- 0022-3263
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
Asymmetric Hydrogenation of β-Ketophosphonates and β-Ketothiophosphonates with Chiral Ru(II) Catalysts. -β-Hydroxyphosphonates (II) and β-hydroxythiophosphonates such as (IV) are synthesized by hydrogenation of the corresponding . beta.-keto compounds (I) and (III). The use of a chiral Ru(II) catal
Asymmetric hydrogenationofphenylthio ketonesusing chiralRu(II) catalystsis reported. Completeconversionsandenantiomericexcessesup to 98%wereobtained.
Enantioselective Hydrogenation of β-Keto Sulfones with Chiral Ru(II)-Catalysts: Synthesis of Enantiomerically Pure Butenolides and γ-Butyrolactones. -A highly enantioselective synthesis of chiral β-hydroxy sulfones (II), (VII) and (XII) is presented involving a novel ruthenium-catalyzed hydrogenati
The first asymmetric hydrogenation of vinylphosphonic acids and esters to the corresponding arylethylphosphonic acids and esters using chiral Ru(ll) catalysts is reported with enantiomeric excesses up to 86%.
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v