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Asymmetric hydrogenation of β-ketophosphonates and β-ketothiophosphonates with chiral ru (II) catalysts

✍ Scribed by Isabelle Gautier; Virginie Ratovelomanana-Vidal; Philippe Savignac; Jean-Pierre Genêt


Book ID
103406759
Publisher
Elsevier Science
Year
1996
Tongue
French
Weight
202 KB
Volume
37
Category
Article
ISSN
0040-4039

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📜 SIMILAR VOLUMES


ChemInform Abstract: Asymmetric Hydrogen
✍ I. GAUTIER; V. RATOVELOMANANA-VIDAL; P. SAVIGNAC; J.-P. GENET 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 32 KB 👁 1 views

Asymmetric Hydrogenation of β-Ketophosphonates and β-Ketothiophosphonates with Chiral Ru(II) Catalysts. -β-Hydroxyphosphonates (II) and β-hydroxythiophosphonates such as (IV) are synthesized by hydrogenation of the corresponding . beta.-keto compounds (I) and (III). The use of a chiral Ru(II) catal

Asymmetric Hydrogenation of Phenylthio K
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Asymmetric hydrogenationofphenylthio ketonesusing chiralRu(II) catalystsis reported. Completeconversionsandenantiomericexcessesup to 98%wereobtained.

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The first asymmetric hydrogenation of vinylphosphonic acids and esters to the corresponding arylethylphosphonic acids and esters using chiral Ru(ll) catalysts is reported with enantiomeric excesses up to 86%.

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