1998 organo-phosphorus compounds, isocyclic C derivatives organo-phosphorus compounds, isocyclic C derivatives S 0084 ## 32 -228 Asymmetric Hydrogenation of Vinylphosphonic Acids and Esters with Chiral Ru(II) Catalysts. -The first asymmetric catalytic hydrogenation of vinylphosphonic acids (I) is
Asymmetric hydrogenation of vinylphosphonic acids and esters with chiral Ru(II) catalysts
✍ Scribed by J.-C. Henry; D. Lavergne; V. Ratovelomanana-Vidal; J.-P. Genêt; I.P. Beletskaya; T.M. Dolgina
- Book ID
- 104259174
- Publisher
- Elsevier Science
- Year
- 1998
- Tongue
- French
- Weight
- 241 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
The first asymmetric hydrogenation of vinylphosphonic acids and esters to the corresponding arylethylphosphonic acids and esters using chiral Ru(ll) catalysts is reported with enantiomeric excesses up to 86%.
📜 SIMILAR VOLUMES
Asymmetric hydrogenationofphenylthio ketonesusing chiralRu(II) catalystsis reported. Completeconversionsandenantiomericexcessesup to 98%wereobtained.
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v
Asymmetric Hydrogenation of β-Ketophosphonates and β-Ketothiophosphonates with Chiral Ru(II) Catalysts. -β-Hydroxyphosphonates (II) and β-hydroxythiophosphonates such as (IV) are synthesized by hydrogenation of the corresponding . beta.-keto compounds (I) and (III). The use of a chiral Ru(II) catal