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Electrospray mass spectrometry of stable iminyl nitroxide and nitronyl nitroxide free radicals

✍ Scribed by Craig D. Smith; John P. Bartley; Steven E. Bottle

Publisher
John Wiley and Sons
Year
2002
Tongue
English
Weight
108 KB
Volume
37
Category
Article
ISSN
1076-5174

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✦ Synopsis

Abstract

Electrospray ionization (ESI) mass spectra have been recorded for a range of substituted nitronyl nitroxide and iminyl nitroxide monoradicals and biradicals. Secondary species formed in the ESI source were observed as the dominant ions in both the iminyl nitroxide and nitronyl nitroxide spectra. Daughter ion spectrometry was used to establish fragmentation mechanisms for the nitronyl nitroxide and iminyl nitroxide moieties as well as the secondary species under ESI conditions. Copyright © 2002 John Wiley & Sons, Ltd.

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