## Abstract Electrospray ionization (ESI) mass spectra have been recorded for a range of substituted nitronyl nitroxide and iminyl nitroxide monoradicals and biradicals. Secondary species formed in the ESI source were observed as the dominant ions in both the iminyl nitroxide and nitronyl nitroxide
Mass Spectrometric Study of α-Nitronyl Nitroxides. A Class of Stable Organic Radicals
✍ Scribed by Jesús Orduna; Javier Garín; Christophe Boulle; Joan Cirujeda; Oriol Jürgens; Jaume Veciana
- Publisher
- John Wiley and Sons
- Year
- 1997
- Tongue
- English
- Weight
- 169 KB
- Volume
- 11
- Category
- Article
- ISSN
- 0951-4198
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✦ Synopsis
The electron impact-induced fragmentation of α-nitronyl nitroxides has been studied by exact mass measurements, metastable ion analysis and collisional-induced dissociation. The formation of odd electron ions has been studied in detail in order to ascertain if they are a consequence of bimolecular reactions or an exception to the even-electron rule.
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