## Abstract Electrospray ionization (ESI) mass spectra have been recorded for a range of substituted nitronyl nitroxide and iminyl nitroxide monoradicals and biradicals. Secondary species formed in the ESI source were observed as the dominant ions in both the iminyl nitroxide and nitronyl nitroxide
Mass spectrometry of stable free radicals—II: pyrrolidine nitroxides
✍ Scribed by A. P. Davies; A. Morrison; M. D. Barratt
- Publisher
- John Wiley and Sons
- Year
- 1974
- Tongue
- English
- Weight
- 349 KB
- Volume
- 8
- Category
- Article
- ISSN
- 1076-5174
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Electrospray ionization (ESI) mass spectra were recorded for a range of substituted isoindoline nitroxides, two isoindoline nitroxide dimers and two piperidinyl nitroxides. In all cases the dominant molecular species arise from oxidation rather than protonation, an unusual process in ESI. Fragment i
## Abstract For Abstract see ChemInform Abstract in Full Text.
The electron impact-induced fragmentation of α-nitronyl nitroxides has been studied by exact mass measurements, metastable ion analysis and collisional-induced dissociation. The formation of odd electron ions has been studied in detail in order to ascertain if they are a consequence of bimolecular r