Electronic relaxation of biacetyl in a supersonic jet
โ Scribed by R. Campargue; B. Soep
- Publisher
- Elsevier Science
- Year
- 1979
- Tongue
- English
- Weight
- 279 KB
- Volume
- 64
- Category
- Article
- ISSN
- 0009-2614
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โฆ Synopsis
Emission spectra have been recorded and decay times measured for biacetyl seiectively ewited in the 0: band of the Sr-So ('A,-'Ag) transition_ The spectrum of the "long emission" corresponds to a superposition of the fluorescence and of the "hot" phosphorescence_ The results may be treated in terms of a uniform distriiution of the singlet oscillator strength among the quasi-stationary levels, in the absence of viirational redistrrbution on a microsecond scale.
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The phosphorescence excitation specrra due to trwsitions to rile Sr (II=') srnres of biacetyl, bcnzaldcb~dc and benzophenone in supersonic jets have been measured for the first time by a novel spectroscopic means tlGlizing sensirizcd phos-p11orcsccnce.
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