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Intramolecular electronic energy transfer of bichromophoric molecules in a supersonic free jet

✍ Scribed by Takayuki Ebata; Yasushi Suzuki; Naohiko Mikami; Tsutomu Miyashi; Mitsuo Ito

Publisher: Elsevier Science
Year: 1984
Tongue: English
Weight: 392 KB
Volume: 110
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(84)85470-6

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✦ Synopsis

The intramolecular electronic energy transfer between two chromopliorcs separated by a methylene chain has been observed in an isolated molecule.

The molecules studied are 1 _(o-tolyl)-3-@-tolyl)propane (I) and I-(m-tolyl)-3-@-tolylk propane (II). The energy transfer rate from o-or m-xylcnc moiety to p-.wlenc moiety was found to be 108-10gs-1, which depends on the density of states of bath modes bclonying to the lower-energy moiety.

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