Electronic Communication in [Co2(CO)6]2-Diyne and [Co2(CO)4(dppm)]2-Diyne Complexes

✍ Scribed by Domenico Osella; Luciano Milone; Carlo Nervi; Mauro Ravera

• Publisher: John Wiley and Sons
• Year: 1998
• Tongue: English
• Weight: 164 KB
• Volume: 1998
• Category: Article
• ISSN: 1434-1948
• DOI: 10.1002/(sici)1099-0682(199810)1998:10<1473::aid-ejic1473>3.0.co;2-t

✦ Synopsis

The electrochemical behaviour of the [Co 2 (CO) 6 ] 2 (µ-R-CϵC-through-space and through-bond interactions are operating with different relative weight depending on the spacer L. L-CϵC-R) and [Co 2 (CO) 4 (dppm)] 2 (µ-R-CϵC-L-CϵC-R) series is reported. Qualitative evidence suggests that both