[Cp2Co][Bi{Co(CO)4}4]: A Paramagnetic, Ten-Electron, Tetrahedral Complex of Bismuth
β Scribed by J. Scott Leigh; Dr. Kenton H. Whitmire
- Publisher
- John Wiley and Sons
- Year
- 1988
- Tongue
- English
- Weight
- 375 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0044-8249
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π SIMILAR VOLUMES
The construction of supramolecules or extended frameworks based on coordination and organometallic complexes is one of the major areas of current research in inorganic and organometallic chemistry. Nevertheless, this approach has received little attention in the field of organobismuth Β± transition-
E, they are also not hydrolyzed by conc. hydrochloric acid. 3a-c can be deprotonated with sodium hydroxide and acylated at the nitrogen. Although in the 1,2,4-diazaphospholes a 1,3-diamino-2phosphaallyl system is still formally present, the ring closure is associated with an essential change: the c
## Experimental Section 3: Compound 4 [4] (80 mg, 0.075 mmol) and KC 8 (22 mg, 0.163 mmol) were placed in a reaction tube with a magnetic stirrer. Oxygen-free, dry THF (2 mL) was introduced into the reaction tube by vacuum transfer, and the reaction mixture was stirred at room temperature to produ
Section 3: Compound 4 [4] (80 mg, 0.075 mmol) and KC 8 (22 mg, 0.163 mmol) were placed in a reaction tube with a magnetic stirrer. Oxygen-free, dry THF (2 mL) was introduced into the reaction tube by vacuum transfer, and the reaction mixture was stirred at room temperature to produce a yellow soluti