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A (Tetrasilacyclobutadiene)tricarbonyliron Complex [{η4-(tBu2MeSi)4Si4}Fe(CO)3]: The Silicon Cousin of Pettit's (Cyclobutadiene)tricarbonyliron Complex [(η4-H4C4)Fe(CO)3]

✍ Scribed by Kazunori Takanashi; Vladimir Ya. Lee; Masaaki Ichinohe; Akira Sekiguchi

Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
205 KB
Volume
45
Category
Article
ISSN
0044-8249

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✦ Synopsis

Experimental Section

3: Compound 4 [4] (80 mg, 0.075 mmol) and KC 8 (22 mg, 0.163 mmol) were placed in a reaction tube with a magnetic stirrer. Oxygen-free, dry THF (2 mL) was introduced into the reaction tube by vacuum transfer, and the reaction mixture was stirred at room temperature to produce a yellow solution over 3 h. The solvent was removed in vacuo, and the residue was extracted with degassed hexane. The mixture was filtered to remove the graphite and inorganic salt, and the solution was cooled to À30 8C to produce yellow crystals of 3

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A (Tetrasilacyclobutadiene)tricarbonylir
A (Tetrasilacyclobutadiene)tricarbonyliron Complex [{η4-(tBu2MeSi)4Si4}Fe(CO)3]: The Silicon Cousin of Pettit's (Cyclobutadiene)tricarbonyliron Complex [(η4-H4C4)Fe(CO)3]
✍ Kazunori Takanashi; Vladimir Ya. Lee; Masaaki Ichinohe; Akira Sekiguchi 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 205 KB 👁 1 views

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Equilibrium geometries, bond dissociation energies and relative energies of axial and equatorial iron tetracarbonyl complexes of the general type Fe(CO) 4 L (L = CO, CS, N2, NO + , CN ± , NC ± , g 2 -C 2 H 4 , g 2 -C 2 H 2 , CCH 2 , CH 2 , CF 2 , NH 3 , NF 3 , PH 3 , PF 3 , g 2 -H 2 ) are calculated