Stark polarisierende Co2+ -1onen aus ICo2(COhl und g;ridin in Kohlenwasserstoffen : Synthese und Struktur von [(C0~(C0),,)~{Co(py)~}] und I(cO)4CoCo(pyhlICo(CO)41\*\*
Highly Polarizing Co2+ Ions from [Co2(CO)8] and Pyridine in Hydrocarbons: Synthesis and Structure of [{CO3(CO)10}2{Co(py)4}] and [(CO4CoCo(py)3][Co(CO)4]
β Scribed by Prof. Giuseppe Fachinetti; Dr. Giovanni Fochi; Dr. Tiziana Funaioli; Prof. Pier Francesco Zanazzi
- Publisher
- John Wiley and Sons
- Year
- 1987
- Tongue
- English
- Weight
- 282 KB
- Volume
- 26
- Category
- Article
- ISSN
- 0044-8249
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π SIMILAR VOLUMES
to the parallel arene rings (which are inaccessible from the rear side) of the cyclophane ( B).I". 18] I I By virtue of the q6-bonding, 2 differs markedly from the analogous Menshutkin complexes, in which there is no central c0ordination.1~~ The bonding in 2 can be explained quite well, however, in
W e were interested i n examining s i n g l e c r y s t a l s containing the triruthenium anion I R u ~( ~Y C = ~N ~~) (p-a))3(CO),l-which we obtain q u a n t i t a t i v e l y as t h e quanidinim salt, l a , i n the treatment of R U ~( C O ) ~~ with CfNMe2)4.'1/ When c r y s t a l s of l a proved u