[2 + 2 + 2]-Co-cyclotrimerization 6-Alkynylpurines with Diynes: A Method for Preparation of 6-Arylpurines.
โ Scribed by Pavel Turek; Martin Kotora; Michal Hocek; Ivana Cisarova
- Publisher
- John Wiley and Sons
- Year
- 2003
- Weight
- 173 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0931-7597
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
## Abstract For Abstract see ChemInform Abstract in Full Text.
A reliable route is described for the preparation of various 2-substituted derivatives of [1,2,3,4,4a,8a-13 C 6 ]-naphthalene via the bromide 10. The approach is used to prepare [naphthalene-1,2,3,4,4a,8a-13 C 6 ]-2-(2-bromoethyl)naphthalene (1), a key intermediate in the synthesis of labelled SR577
The reaction of Na 2 [Fe(CO) 4 ] with Br 2 CF 2 in npentane generates a mixture of the compounds (CO) 3 Fe(l-CO) 3ยฑn (l-CF 2 ) n Fe(CO) 3 (2, n = 2; 3, n = 1) in low yields with 3 as the main product. 3 is obtained free from 2 by reacting Br 2 CF 2 with Na 2 [Fe 2 (CO) 8 ]. The non-isolable monomeri