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Electron-Transfer Kinetics for Generation of Organoiron(IV) Porphyrins and the Iron(IV) Porphyrin π Radical Cations

✍ Scribed by Fukuzumi, Shunichi; Nakanishi, Ikuo; Tanaka, Keiko; Suenobu, Tomoyoshi; Tabard, Alain; Guilard, Roger; Van Caemelbecke, Eric; Kadish, Karl M.


Book ID
126092600
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
111 KB
Volume
121
Category
Article
ISSN
0002-7863

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## Abstract The proximal axial ligand in heme iron enzymes plays an important role in tuning the reactivities of iron(IV)‐oxo porphyrin π‐cation radicals in oxidation reactions. The present study reports the effects of axial ligands in olefin epoxidation, aromatic hydroxylation, alcohol oxidation,