𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Redox Potentials of Oxoiron(IV) Porphyrin π-Cation Radical Complexes: Participation of Electron Transfer Process in Oxygenation Reactions

✍ Scribed by Takahashi, Akihiro; Kurahashi, Takuya; Fujii, Hiroshi


Book ID
127154571
Publisher
American Chemical Society
Year
2011
Tongue
English
Weight
1014 KB
Volume
50
Category
Article
ISSN
0020-1669

No coin nor oath required. For personal study only.


📜 SIMILAR VOLUMES


Mechanistic Insights into the Reversible
✍ Woon Ju Song; Ying Ji Sun; Sun Kyung Choi; Wonwoo Nam 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 319 KB 👁 2 views

## Abstract We have shown previously that iodosylbenzene–iron(III) porphyrin intermediates (2) are generated in the reactions of oxoiron(IV) porphyrin π‐cation radicals (1) and iodobenzene (PhI), that 1 and 2 are at equilibrium in the presence of PhI, and that the epoxidation of olefins by 2 afford

Enhanced Reactivities of Iron(IV)-Oxo Po
✍ Yaeun Kang; Hui Chen; Yu Jin Jeong; Wenzhen Lai; Eun Hae Bae; Sason Shaik; Wonwo 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 583 KB

## Abstract The proximal axial ligand in heme iron enzymes plays an important role in tuning the reactivities of iron(IV)‐oxo porphyrin π‐cation radicals in oxidation reactions. The present study reports the effects of axial ligands in olefin epoxidation, aromatic hydroxylation, alcohol oxidation,