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Solution spectroscopic studies of electrolytically generated iron(III) and iron(IV) tetrakis(2,6-difluorophenyl)porphyrin .pi. cation radicals

✍ Scribed by Nanthakumar, Alaganandan.; Goff, Harold M.


Book ID
120308076
Publisher
American Chemical Society
Year
1991
Tongue
English
Weight
629 KB
Volume
30
Category
Article
ISSN
0020-1669

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High-valent oxo-iron(IV) species are commonly proposed as the key intermediates in the catalytic mechanisms of iron enzymes. Water-soluble iron(III) tetrakis-5,10,15,20-(N-methyl-4-pyridyl)porphyrin (Fe(III)TMPyP) has been used as a model of heme-enzyme to catalyse the hydrogen peroxide (H 2 O 2 ) o