ChemInform Abstract: Electrochemical Syn
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U. Hess; H. Brosig; J. Komenda
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Article
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2010
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John Wiley and Sons
⚖ 29 KB
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Electrochemical Synthesis of Isocyanides and 1,n-Diisocyanides. -Electrolysis of tosylmethylisocyanides (I) and (III) gives the new alkyl-, aryl-, and 1,n-diisocyanides (II) and (IV) in high purity and in moderate to good yields. The reaction proceeds in a two-electron C,S cleavage, reducing exclusi