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Synthesis of glycosyl isocyanides
β Scribed by P. Boullanger; D. Marmet; G. Descotes
- Publisher
- Elsevier Science
- Year
- 1979
- Tongue
- French
- Weight
- 560 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0040-4020
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π SIMILAR VOLUMES
Synthesis of mono-and diglycosyl diglycerides with natural structure from 1,2-di-O-acyl-snglycerols, 1,2-O-isopropylidene-sn-glycerol, 2,5-methylene-D-mannitol by the orthoester method of glycosylation is reported. \* Translated by A.L. Pumpiansky, Moscow. \* The molar ratio of orthoester, alcohols
Glycals undergo smooth carbon-Ferrier rearrangement with isocyanides in the presence of a catalytic amount of FeCl 3 under mild reaction conditions to provide C-glycosyl amides in good yields with high a-selectivity. The use of FeCl 3 makes this method simple, convenient and cost-effective. This is