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ChemInform Abstract: Electrochemical Generation of Alkyl and Aryl Isocyanides.

โœ Scribed by Antonio Guirado; Andres Zapata; Jesus L. Gomez; Luis Trabalon; Jesus Galvez


Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
30
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Electrochemical Syn
โœ U. Hess; H. Brosig; J. Komenda ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 29 KB

Electrochemical Synthesis of Isocyanides and 1,n-Diisocyanides. -Electrolysis of tosylmethylisocyanides (I) and (III) gives the new alkyl-, aryl-, and 1,n-diisocyanides (II) and (IV) in high purity and in moderate to good yields. The reaction proceeds in a two-electron C,S cleavage, reducing exclusi