Electrocapillary studies of hexafluoro-2-propanol on mercury
✍ Scribed by Rodolfo Pedriali; Jaroslav K∪ta
- Publisher
- Elsevier Science
- Year
- 1974
- Weight
- 356 KB
- Volume
- 51
- Category
- Article
- ISSN
- 0022-0728
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## Abstract In spite of its low nucleophilicity, hexafluoro‐2‐propanol easily adds to vinyl ethers, without catalyst, to afford a range of hexafluoroisopropyloxy acetals. This addition reaction also occurred in the presence of a competitive, more nucleophilic alcohol. Kinetic studies showed the imp
A facile, selective and efficient method for the oxidation of sulfides to sulfoxides by aqueous 30% H202 in hexafluoro-2-propanol at room temperature is described. Specific role of the solvent in the selectivity is exhibited.
Methyltrioxorhenium-catalysed epoxidation of alkenes with hydrogen peroxide can be improved by using hexafluoro-2propanol as a solvent. Quantitative conversions of cyclic and terminal olefins can be obtained with only 30% H 2 O 2 and 0.1 mol% of catalyst.