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Methyltrioxorhenium-catalysed epoxidation of alkenes: enhancement of reactivity in hexafluoro-2-propanol

✍ Scribed by Jernej Iskra; Danièle Bonnet-Delpon; Jean-Pierre Bégué

Book ID: 104232357
Publisher: Elsevier Science
Year: 2002
Tongue: French
Weight: 138 KB
Volume: 43
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)02316-4

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✦ Synopsis

Methyltrioxorhenium-catalysed epoxidation of alkenes with hydrogen peroxide can be improved by using hexafluoro-2propanol as a solvent. Quantitative conversions of cyclic and terminal olefins can be obtained with only 30% H 2 O 2 and 0.1 mol% of catalyst.

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