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A selective conversion of sulfide to sulfoxide in hexafluoro-2-propanol

✍ Scribed by K.S. Ravikumar; Jean-Pierre Bégué; Danièle Bonnet-Delpon

Publisher
Elsevier Science
Year
1998
Tongue
French
Weight
210 KB
Volume
39
Category
Article
ISSN
0040-4039

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✦ Synopsis

A facile, selective and efficient method for the oxidation of sulfides to sulfoxides by aqueous 30% H202 in hexafluoro-2-propanol at room temperature is described. Specific role of the solvent in the selectivity is exhibited.

📜 SIMILAR VOLUMES

Role of Hexafluoro-2-propanol in Selecti
Role of Hexafluoro-2-propanol in Selective Oxidation of Sulfide to Sulfoxide: Efficient Preparation of Glycosyl Sulfoxides
✍ K. S. Ravikumar; Yong Min Zhang; Jean-Pierre Bégué; Danièle Bonnet-Delpon 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 119 KB 👁 2 views

Aqueous 30% H 2 O 2 in hexafluoro-2-propanol (HFIP) is carbon double bond are shown to not be affected by the reagent system used. The oxidation of glycosyl sulfides to described as a facile, selective and efficient oxidant for the conversion of sulfides to sulfoxides under neutral conditions. glyco