Woygang Meyer zu Reckendorf Diaminozucker, 1x1) Synthese der 3-Amino-3-desox yund 3.6-Diamino-3.6-didesox y-D-glucose \*) Aus dem Institut fur Pharmazeutische Chemie der Universitat Munster (Eingegangen am 20. Mai 1968) Die Synthese der beiden Aminozucker erfolgt durch Substitution am C-3 des D-Allo
Ein Phenothiazin-Derivat der 3.6-Diamino-3.6-didesoxy-D-glucose. Di- und Polyaminozucker, XVII
✍ Scribed by Prof. Dr. W. Zu Meyer Reckendorf
- Publisher
- John Wiley and Sons
- Year
- 1972
- Tongue
- English
- Weight
- 194 KB
- Volume
- 305
- Category
- Article
- ISSN
- 0365-6233
No coin nor oath required. For personal study only.
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**Di‐ and Polyamino Sugars, XXIII. Elimination Reactions Accompanying the Synthesis of 2,3‐Diamino‐2,3‐dideoxy‐D‐glucose** By‐products of the synthesis of 2,3‐diamino‐2,3‐dideoxy‐D‐glucose were found to be hex‐2‐ and ‐3‐enopyranosides (**4, 5**). Structure proofs by spectroscopy were corroborated b
## Abstract Die Titelverbindung wurde durch Einführung von zwei Stickstoff‐Funktionen in die 2,3‐Diamino‐2,3‐didesoxy‐D‐glucose dargestellt. Anstelle des freien Zuckers erhielten wir hauptsächlich das Pyrrolidin **17**.
## Synthesis of 2.3.4.6-Tetraamino-2.3.4.6-tetradeoxy-~-galactose Benzyl 2-acetamido-2-deoxy-a-~-glucopyranoside was converted into the corresponding allo derivative which was trlmesylared and reacted with sodium azide in phosphoric tris-(dimethylamide). After deblocking the free sugar was isolate