**Di‐ and Polyamino Sugars, XXIII. Elimination Reactions Accompanying the Synthesis of 2,3‐Diamino‐2,3‐dideoxy‐D‐glucose** By‐products of the synthesis of 2,3‐diamino‐2,3‐dideoxy‐D‐glucose were found to be hex‐2‐ and ‐3‐enopyranosides (**4, 5**). Structure proofs by spectroscopy were corroborated b
✦ LIBER ✦
Di- und Polyaminozucker, XV. Synthese der 2.4-Diamino-l.6-anhydro-2.4-didesoxy-D-talose
✍ Scribed by zu Reckendorf, Wolfgang Meyer
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1970
- Tongue
- English
- Weight
- 229 KB
- Volume
- 103
- Category
- Article
- ISSN
- 0009-2940
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## Synthesis of 2.3.4.6-Tetraamino-2.3.4.6-tetradeoxy-~-galactose Benzyl 2-acetamido-2-deoxy-a-~-glucopyranoside was converted into the corresponding allo derivative which was trlmesylared and reacted with sodium azide in phosphoric tris-(dimethylamide). After deblocking the free sugar was isolate
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## Abstract Die Titelverbindung wurde durch Einführung von zwei Stickstoff‐Funktionen in die 2,3‐Diamino‐2,3‐didesoxy‐D‐glucose dargestellt. Anstelle des freien Zuckers erhielten wir hauptsächlich das Pyrrolidin **17**.
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