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Efficient stereoselective synthesis of α-C-glycopyranosides using 2,2′-azobis(2,4-dimethyl-4-methoxyvaleronitrile) [V-70]

✍ Scribed by Kentoku Gotanda; Masato Matsugi; Miki Suemura; Chiyo Ohira; Atsunori Sano; Masahisa Oka; Yasuyuki Kita

Book ID: 104209555
Publisher: Elsevier Science
Year: 1999
Tongue: French
Weight: 624 KB
Volume: 55
Category: Article
ISSN: 0040-4020
DOI: 10.1016/s0040-4020(99)00587-6

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✦ Synopsis

Abslma: Efticient synthesis of a-C-glycopyranosides through a radical addition reaction using 2.2'~axobis(2,4dimethy@methoxyvaleronitrile) [V-70] as an initiator under mild condition was developed. This method made it possible to completely control the stereocenter at the anomeric position and obtain only the aanomer in high yield compared with AJBN, EtJB, and photo irradiation methods.

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