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ChemInform Abstract: Practical Radical Additions under Mild Conditions Using 2,2′-Azobis(2,4-dimethyl-4-methoxyvaleronitrile) [V-70] as an Initiator.

✍ Scribed by Y. KITA; K. GOTANDA; K. MURATA; M. SUEMURA; A. SANO; T. YAMAGUCHI; M. OKA; M. MATSUGI

Publisher: John Wiley and Sons
Year: 2010
Weight: 37 KB
Volume: 29
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199848033

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A Highly Stereoselective Synthesis of α-Linked C-Glycopyranosides Using 2,2'-Azobis-(2,4-dimethyl-4-methoxyvaleronitrile) (V-70). -By using V-70 as an effective radical initiator at low temperature, a highly α-selective synthesis of C-glycopyranosides (III) is realized. -(KITA, Y.;