ChemInform Abstract: A Highly Stereoselective Synthesis of α-Linked C-Glycopyranosides Using 2,2′-Azobis-(2,4-dimethyl-4-methoxyvaleronitrile) (V-70).

✍ Scribed by Y. KITA; K. GOTANDA; A. SANO; M. OKA; K. MURATA; M. SUEMURA; M. MATSUGI

• Publisher: John Wiley and Sons
• Year: 2010
• Weight: 33 KB
• Volume: 29
• Category: Article
• ISSN: 0931-7597
• DOI: 10.1002/chin.199808198

✦ Synopsis

A Highly Stereoselective Synthesis of α-Linked C-Glycopyranosides Using 2,2'-Azobis-(2,4-dimethyl-4-methoxyvaleronitrile) (V-70).

-By using V-70 as an effective radical initiator at low temperature, a highly α-selective synthesis of C-glycopyranosides (III) is realized. -(KITA, Y.;