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ChemInform Abstract: Highly Stereoselective Synthesis of Carbocycles via a Radical Addition Reaction Using 2,2′-Azobis(2,4-dimethyl-4-methoxyvaleronitrile) [V-70L].

✍ Scribed by Masato Matsugi; Kentoku Gotanda; Chiyo Ohira; Miki Suemura; Atsunori Sano; Yasuyuki Kita

Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
31
Category
Article
ISSN
0931-7597

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ChemInform Abstract: A Highly Stereosele
ChemInform Abstract: A Highly Stereoselective Synthesis of α-Linked C-Glycopyranosides Using 2,2′-Azobis-(2,4-dimethyl-4-methoxyvaleronitrile) (V-70).
✍ Y. KITA; K. GOTANDA; A. SANO; M. OKA; K. MURATA; M. SUEMURA; M. MATSUGI 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 33 KB

A Highly Stereoselective Synthesis of α-Linked C-Glycopyranosides Using 2,2'-Azobis-(2,4-dimethyl-4-methoxyvaleronitrile) (V-70). -By using V-70 as an effective radical initiator at low temperature, a highly α-selective synthesis of C-glycopyranosides (III) is realized. -(KITA, Y.;