## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
Efficient Redox Isomerization of Allylic Alcohols under Mild Conditions Catalyzed by Arene−Ruthenium(II) Complexes
✍ Scribed by Crochet, Pascale; Fernández-Zúmel, Mariano A.; Gimeno, José; Scheele, Marcus
- Book ID
- 126827390
- Publisher
- American Chemical Society
- Year
- 2006
- Tongue
- English
- Weight
- 64 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0276-7333
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## Abstract A dicationic dichloro‐bipyridine‐ruthenium complex shows very high catalytic activity in redox isomerization of allylic alcohols but a relatively low one in transfer hydrogenation of ketones; surprisingly, the analogous dimethyl‐bipyridine‐ruthenium complex shows reverse catalytic activ
## Abstract A Ru(II)—dichlorobipyridine complex (Ia) efficiently catalyzes the redox isomerization of terminal and internal allylic alcohols to give the corresponding ketones, e.g. (III), (V) or (VII), in high to excellent conversion.
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
Aromatic and alkyl alcohols were oxidized to the corresponding aldehydes or ketones at room temperature with high conversion and selectivity to the desired products of 100% using iodosylbenzene as oxidant catalyzed by ruthenium complexes Phen-Ru-Phen, Phen-Ru-Bipy, Phen-Ru-Quin, Quin-Ru-Quin and Bip