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Oxidation of alcohols using iodosylbenzene as oxidant catalyzed by ruthenium complexes under mild reaction conditions

โœ Scribed by Zhi Wang Yang; Qiao Xiang Kang; Feng Quan; Zi Qiang Lei

Book ID
104057119
Publisher
Elsevier Science
Year
2007
Tongue
English
Weight
157 KB
Volume
261
Category
Article
ISSN
1381-1169

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โœฆ Synopsis

Aromatic and alkyl alcohols were oxidized to the corresponding aldehydes or ketones at room temperature with high conversion and selectivity to the desired products of 100% using iodosylbenzene as oxidant catalyzed by ruthenium complexes Phen-Ru-Phen, Phen-Ru-Bipy, Phen-Ru-Quin, Quin-Ru-Quin and Bipy-Ru-Quin (where Phen = 1,10-phenanthroline, Quin = 8-hydroxyquinoline, Bipy = 2,2 -bipyridine). The reaction conditions are mild, the ligands used in this oxidation system are commercially available and the procedure for the preparation of the complexes is very simple.

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