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Efficient and selective carbon-hydrogen activation by a tris(pyrazolylborate)rhodium complex

✍ Scribed by Ghosh, Chanchal K.; Graham, William A. G.

Book ID
125968280
Publisher
American Chemical Society
Year
1987
Tongue
English
Weight
292 KB
Volume
109
Category
Article
ISSN
0002-7863

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Carbon–Hydrogen Bond Activation of Arene
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✍ Jun-ichi Ito; Hisao Nishiyama 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 144 KB 👁 1 views

## Abstract Thermolysis of the rhodium(III) complex [(__dm__‐Phebox‐__dm__)Rh(OAc)~2~(H~2~O)] [1; __dm__‐Phebox‐__dm__ = 2,6‐bis(4,4‐dimethyloxazolinyl)phenyl] in various arenes results in the formation of the corresponding aryl complexes [(__dm__‐Phebox‐__dm__)Rh(Ar)(κ^2^‐OAc)] [Ar = C~6~H~5~ (2),