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Competitive carbon-hydrogen activation and C.tplbond.C coordination in the reactions of acetylenes with a binuclear rhodium complex

โœ Scribed by Berry, Donald H.; Eisenberg, Richard


Book ID
126184663
Publisher
American Chemical Society
Year
1985
Tongue
English
Weight
380 KB
Volume
107
Category
Article
ISSN
0002-7863

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Isomerization of linear C3H3+in its reac
โœ Mehdi Moini ๐Ÿ“‚ Article ๐Ÿ“… 1992 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 562 KB

The isomerization of linear C3H 3 (+) in its reaction with acetylene to cyclic C3H 3 (+) was studied with a quadrupole ion trap mass spectrometer. The reaction of linear C3H 3 (+) with (13)C2H2 shows that isomerization takes place via a [C5H 5 (+) ](\*) activated complex that is unstable relative to