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Carbon−Hydrogen and Carbon−Carbon Bond Activation of Cyclopropane by a Hydridotris(pyrazolyl)borate Rhodium Complex

✍ Scribed by Wick, Douglas D.; Northcutt, Todd O.; Lachicotte, Rene J.; Jones, William D.

Book ID: 127378616
Publisher: American Chemical Society
Year: 1998
Tongue: English
Weight: 176 KB
Volume: 17
Category: Article
ISSN: 0276-7333
DOI: 10.1021/om971066e

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## Abstract Thermolysis of the rhodium(III) complex [(__dm__‐Phebox‐__dm__)Rh(OAc)~2~(H~2~O)] [1; __dm__‐Phebox‐__dm__ = 2,6‐bis(4,4‐dimethyloxazolinyl)phenyl] in various arenes results in the formation of the corresponding aryl complexes [(__dm__‐Phebox‐__dm__)Rh(Ar)(κ^2^‐OAc)] [Ar = C~6~H~5~ (2),