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Carbon-hydrogen bond activation by rhodium and iridium amides: strategy vs. serendipity

✍ Scribed by Fryzuk, Michael D.; MacNeil, Patricia A.; McManus, Neil T.


Book ID
126302519
Publisher
American Chemical Society
Year
1987
Tongue
English
Weight
402 KB
Volume
6
Category
Article
ISSN
0276-7333

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## Abstract Thermolysis of the rhodium(III) complex [(__dm__‐Phebox‐__dm__)Rh(OAc)~2~(H~2~O)] [1; __dm__‐Phebox‐__dm__ = 2,6‐bis(4,4‐dimethyloxazolinyl)phenyl] in various arenes results in the formation of the corresponding aryl complexes [(__dm__‐Phebox‐__dm__)Rh(Ar)(κ^2^‐OAc)] [Ar = C~6~H~5~ (2),