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Effect of strain on singlet oxygen (1O2) reactions. 2. Photooxidation of methylenecyclopropanes

✍ Scribed by Frimer, Aryeh A.; Farkash, Tovah; Sprecher, Milon


Book ID
126116672
Publisher
American Chemical Society
Year
1979
Tongue
English
Weight
960 KB
Volume
44
Category
Article
ISSN
0022-3263

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Reaction of singlet oxygen with 2-cyclop
✍ Byoung-Mog Kwon; Richard C. Kanner; Christopher S. Foote πŸ“‚ Article πŸ“… 1989 πŸ› Elsevier Science 🌐 French βš– 262 KB

The reaction of singlet oxygen with 2-cyclopenten-l-one derivatives is regioselective. Reactivity toward singlet oxygen is not solely determined by the conformation of the carbonyl group relative to the olefinic double bond, since even some s-tran.s derivatives are reasonably reactive.