Reaction of singlet oxygen with 2-cyclopenten-1-ones
โ Scribed by Byoung-Mog Kwon; Richard C. Kanner; Christopher S. Foote
- Publisher
- Elsevier Science
- Year
- 1989
- Tongue
- French
- Weight
- 262 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0040-4039
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โฆ Synopsis
The reaction of singlet oxygen with 2-cyclopenten-l-one derivatives is regioselective. Reactivity toward singlet oxygen is not solely determined by the conformation of the carbonyl group relative to the olefinic double bond, since even some s-tran.s derivatives are reasonably reactive.
๐ SIMILAR VOLUMES
## Abstract The reaction of singlet oxygen with 2โphenylnorbornene (**1**) in aprotic solvents gives 3โformylcyclopentyl phenyl ketone (**2**) (10%) and uncharacterized polymer (90%). When methanol is used as solvent, __endo__โ2โphenylโ__exo__โ2โmethoxyโ__exo__โ3โhydroperoxynorbornane (**4**) and _
## Per-on Preaa.