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On the Effect of 1,4-Diazabicyclo[2.2.2]octane on the Singlet-Oxygen Dimol Emission: Chemical Generation of ( 1 O 2 ) 2 in Peroxide Reactions

โœ Scribed by Kazakov, Dmitri V.; Kazakov, Valeri P.; Maistrenko, Gulchekhra Ya.; Mal'zev, Dmitri V.; Schmidt, Reinhard

Book ID
120988505
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
125 KB
Volume
111
Category
Article
ISSN
1089-5639

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Quantification of singlet oxygen generated by thermolysis of 3,3'-(1,4-naphthylene)dipropionate endoperoxide. Monomol and dimol photoemission and the effects of 1,4-diazabicyclo[2.2.2]octane
โœ Di Mascio, Paolo; Sies, Helmut ๐Ÿ“‚ Article ๐Ÿ“… 1989 ๐Ÿ› American Chemical Society ๐ŸŒ English โš– 667 KB

Singlet oxygen arising from the thermal decomposition of the water-soluble endoperoxide of 3,3'-( 1,4-naphthy1idene)dipropionate (NDP02) or from hypochlorite/H202 was detected. Direct measurements of light emission due to the chemiluminescent transition of O2 ('A,) to the triplet ground state was mo