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Reaction of singlet oxygen with methylenecyclopropanes: Formation of 4-methylene-1,2-dioxolanes

โœ Scribed by Takeshi Akasaka; Wataru Ando


Book ID
108382828
Publisher
Elsevier Science
Year
1987
Tongue
French
Weight
254 KB
Volume
28
Category
Article
ISSN
0040-4039

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SnC14-mediated reaction of ozonides (1,2,4-trioxolanes) with aUyltrimethylsilane furnishes trimethylsilylmethyl-l,2-dioxolanes via metalated carbonyl oxides. The carbonyl oxides can arise through initial ionization of either the ether or peroxide oxygens.