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Effect of Solvents on the Product Distribution and Reaction Rate of a Buchwald−Hartwig Amination Reaction

✍ Scribed by Christensen, Henrik; Kiil, Søren; Dam-Johansen, Kim; Nielsen, Ole; Sommer, Michael B.

Book ID
120243743
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
163 KB
Volume
10
Category
Article
ISSN
1083-6160

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Effect of Solvents on the Product Distri
Effect of Solvents on the Product Distribution and Reaction Rate of a Buchwald−Hartwig Amination Reaction
✍ Christensen, Henrik; Kiil, Søren; Dam-Johansen, Kim; Nielsen, Ole; Sommer, Micha 📂 Article 📅 2006 🏛 American Chemical Society 🌐 English ⚖ 163 KB

The Buchwald-Hartwig amination reaction between p-bromotoluene and piperazine in the presence of the homogeneous catalytic system Pd(dba) 2 /(()-BINAP and the base NaO-t-Bu was investigated in two different classes of solvents: aprotic, nonpolar and aprotic, polar. The reaction was carried out using