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A Pronounced Anionic Effect in the Pd-Catalyzed Buchwald—Hartwig Amination Reaction Revealed in Phosphonium Salt Ionic Liquids.

✍ Scribed by James McNulty; Sreedhar Cheekoori; Timothy P. Bender; Jennifer A. Coggan


Publisher
John Wiley and Sons
Year
2007
Weight
20 KB
Volume
38
Category
Article
ISSN
0931-7597

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A Pronounced Anionic Effect in the Pd-Ca
✍ James McNulty; Sreedhar Cheekoori; Timothy P. Bender; Jennifer A. Coggan 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 107 KB

## Abstract The Pd‐mediated Buchwald–Hartwig amination reaction of aryl halides in a phosphonium salt ionic liquid consisting of a trihexyl(tetradecyl)phosphonium cation with a range of anions has been investigated. A pronounced anionic effect was uncovered with the reaction proceeding readily with