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Applicability of a Fiber-Supported Catalyst on a Buchwald–Hartwig Amination Reaction

✍ Scribed by Christensen, Henrik; Kiil, Søren; Dam-Johansen, Kim; Nielsen, Ole

Book ID
121282744
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
587 KB
Volume
11
Category
Article
ISSN
1083-6160

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✍ Christensen, Henrik; Kiil, Søren; Dam-Johansen, Kim; Nielsen, Ole; Sommer, Micha 📂 Article 📅 2006 🏛 American Chemical Society 🌐 English ⚖ 163 KB

The Buchwald-Hartwig amination reaction between p-bromotoluene and piperazine in the presence of the homogeneous catalytic system Pd(dba) 2 /(()-BINAP and the base NaO-t-Bu was investigated in two different classes of solvents: aprotic, nonpolar and aprotic, polar. The reaction was carried out using