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Effect of solvent viscosity on the heme-pocket dynamics of photolyzed (carbonmonoxy)hemoglobin

โœ Scribed by Findsen, E. W.; Friedman, J. M.; Ondrias, M. R.


Book ID
126244769
Publisher
American Chemical Society
Year
1988
Tongue
English
Weight
773 KB
Volume
27
Category
Article
ISSN
0006-2960

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Porphyrin dynamics in the heme-pockets o
โœ C.A. Royer; B. Alpert ๐Ÿ“‚ Article ๐Ÿ“… 1987 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 637 KB

Fluorescence polarization measurements of protoporphyrin embedded in the heme-pockets of myoglobin and hemoglobin reveal three different rotational regimes of the porphyrin which are temperature-dependent. At very low temperatures, porphyrin motions in the cavity depend upon the viscosity of the ext