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Effect of diabatic correlation on the reactions of O(2 3P, 2 1D) with N2 O and CO2

✍ Scribed by J.R. Wiesenfeld

Publisher: Elsevier Science
Year: 1977
Tongue: English
Weight: 471 KB
Volume: 45
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(77)80296-0

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✦ Synopsis

Akhougfi correlation diagrams based upon the appkation of spin and angular momentum conservation have been shown to be a useFu1 device in interpreting the chemistry of electronically excited atoms. experimental observations suggest that a more complete understanding of such chemical processes requires some insight into the electronic structure of the collision complex. In the absence of such information, it is possible to consider the role of diabatic correlations on the energetics of elementary processes with a view toward analyzing the behavior of the reactants along the reaction coordinate. Here, the aeronomically interesting reactions of ground state and electronically excited oxygen atoms with N20 and CO2 areanalyzed and the effects of low-lying molecular excited states on-the reactivity of these

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