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Effect of CH3CN–H2O and CH3CN solvents on rate of reaction of phthalimide with piperidine

✍ Scribed by M. Niyaz Khan

Publisher
John Wiley and Sons
Year
1999
Tongue
English
Weight
89 KB
Volume
12
Category
Article
ISSN
0894-3230

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✦ Synopsis

Pseudo-first-order rate constants (k obs ) for the reaction of piperidine with phthalimide vary linearly with the total concentration of piperidine ([Pip] T ) at a constant content of CH 3 CN in H 2 O-CH 3 CN solvents within the CH 3 CN content range 2-80 % (v/v). The change in k obs with the change in [Pip] T at 100% (v/v) CH 3 CN obeys the relationship k obs = É [Pip] T 2 /(1 Φ [Pip] T ).

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