✦ LIBER ✦

The Reactions of Zn(CF3)Br · 2 CH3CN with Phenol, Pentafluorophenol, their Potassium and Ammonium Salts

✍ Scribed by Sergej V. Pasenok; Yurii L. Yagupolskii; Wieland Tyrra; Dieter Naumann

Publisher: John Wiley and Sons
Year: 1999
Tongue: German
Weight: 74 KB
Volume: 625
Category: Article
ISSN: 0372-7874
DOI: 10.1002/(sici)1521-3749(199905)625:5<831::aid-zaac831>3.0.co;2-0

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✦ Synopsis

Triphenoxymethane, tris(pentafluorophenoxy)methane, phenyl(difluoromethyl)ethers, and tetrakis(pentafluorophenoxy)ethene were prepared via carbenoid reactions of Zn(CF 3 )Br ´2 CH 3 CN and the corresponding phenol or the potassium or ammonium salts in the presence of the auxiliary acid BF 3 ´O(CH 3 ) 2 . The products were identified by their melting and boiling points and in part by their NMR and mass spectra as well as elemental analysis.

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